Formation of the Wiesloch Mississippi Valley-type Zn-Pb-Ag deposit in the extensional setting of the Upper Rhinegraben, SW Germany   总被引：2，自引：0，他引：2  

Katharina Pfaff  Ludwig H. Hildebrandt  David L. Leach  Dorrit E. Jacob  Gregor Markl 《Mineralium Deposita》2010,45(7):647-666

The Mississippi Valley-type (MVT) Zn–Pb–Ag deposit in the Wiesloch area, Southwest Germany, is controlled by graben-related faults of the Upper Rhinegraben. Mineralization occurs as vein fillings and irregular replacement ore bodies consisting of sphalerite, banded sphalerite, galena, pyrite, sulfosalts (jordanite and geocronite), barite, and calcite in the Middle Triassic carbonate host rock. Combining paragenetic information, fluid inclusion investigations, stable isotope and mineral chemistry with thermodynamic modeling, we have derived a model for the formation of the Wiesloch deposit. This model involves fluid mixing between ascending hot brines (originating in the crystalline basement) with sedimentary formation waters. The ascending brines originally had a near-neutral pH (around 6) and intermediate oxidation state, reflecting equilibrium with granites and gneisses in the basement. During fluid ascent and cooling, the pH of the brine shifted towards more acidic (around 4) and the oxidation state increased to conditions above the hematite-magnetite buffer. These chemical characteristics contrast strongly with those of the pore and fracture fluid residing in the limestone aquifer, which had a pH between 8 and 9 in equilibrium with calcite and was rather reduced due to the presence of organic matter in the limestone. Mixing between these two fluids resulted in a strong decrease in the solubility of silver-bearing sphalerite and galena, and calcite. Besides Wiesloch, several Pb–Zn deposits are known along the Upper Rhinegraben, including hydrothermal vein-type deposits like Badenweiler and the Michael mine near Lahr. They all share the same fluid origin and formation process and only differ in details of their host rock and fluid cooling paths. The mechanism of fluid mixing also seems to be responsible for the formation of other MVT deposits in Europe (e.g., Réocin, Northern Spain; Trèves, Southern France; and Cracow-Silesia, Poland), which show notable similarities in terms of their age, mineralogy. and mineral chemistry to the MVT deposit near Wiesloch.  相似文献   

Mullite-corundum-spinel-cordierite-plagioclase xenoliths in the Skaergaard Marginal Border Group: multi-stage interaction between metasediments and basaltic magma   总被引：1，自引：0，他引：1  

Gregor?MarklEmail author 《Contributions to Mineralogy and Petrology》2005,149(2):196-215

Metapelitic country rocks were contact- and pyro-metamorphosed by the Tertiary Skaergaard Intrusion, East Greenland. In an initial stage of heating, while they were probably still in place within the host rock contact aureole, they overstepped a range of equilibrium and disequilibrium melting reactions and produced both a granitic melt and very refractory spinel+cordierite+plagioclase±corundum residuals. Parts of these refractory rocks were then subjected to another melting event after being entrained as xenoliths into the Skaergaard Marginal Border Group, where they experienced a temperature of about 1,000°C at a pressure of about 650 bars and at an oxygen fugacity about 0.2–0.5 log units below the FMQ buffer. Here, they underwent bulk melting, but did not mix with the Skaergaard magma, presumably because of the high viscosity contrast. The Al-rich melts crystallized to an assemblage of corundum+mullite+sillimanite+ plagioclase+spinel+rutile±tridymite±cordierite and they reacted with the surrounding basalt producing a strongly cryptically zoned rim of plagioclase (An₅₅ close to the basalt to An₉₀ close to the Al-rich melt). The assemblage in the inner parts of the xenoliths provides textural evidence for disequilibrium growth due to slow diffusivities in the highly viscous, probably water-free Al-rich melt. Later interaction of lower temperature ferrobasaltic to granophyric melts with the xenoliths along their margins and along cracks led to consumption of corundum and mullite and to the stable assemblage of spinel+cordierite+plagioclase+quartz+K-feldspar +magnetite+ilmenite at about 800°C.  相似文献   

Spatial dependence of the pitch-angle and associated spatial diffusion coefficients for cosmic rays in interplanetary space     

Heinrich J. Völk  Gregor Morfill  Werner Alpers  Martin A. Lee 《Astrophysics and Space Science》1974,26(2):403-430

The spatial dependence of the pitch-angle and associated spatial diffusion coefficients for cosmic ray particles in interplanetary space is calculated in the WKB approximation. The model considers only Alfven waves of solar origin to be responsible for scattering of moderate energy particles. After developing the general theory results are presented for the asymptotic case corresponding to radial distancesr greater than about 1 to 2 AU. The radial diffusion coefficient _r increases with energyE like _r E , wherev2/3. The radial mean free path turns out to increase proportional tor ³ at medium and low heliographic latitudes. This behaviour is consistent with a very small radial cosmic ray gradient and the existence of a free boundary for particle diffusion. At equal radial distances the high latitude mean free path is not only much smaller than the one calculated at the lower latitudes but in addition increases only weakly with distance. Some conceivable dynamical implications for the outer solar system are indicated.  相似文献   

Coagulation and settling of dust in a turbulent protoplanetary disk     

Michael F. Sterzik  Gregor E. Morfill  Berengere Dubrulle 《Astrophysics and Space Science》1995,224(1-2):567-568

We apply our analytic model for the dust diffusivity to calculate the vertical structure of the dust sub-disk in a turbulent protoplanetary nebula. We present a numerical solution of a vertical dust settling equationand a coagulation equation for dust grains covering four orders of magnitude in time and grain size.  相似文献   

Шестидесятилетие проф. Д-ра микулаша кончека     

Alois Gregor 《Studia Geophysica et Geodaetica》1960,4(4):416-417

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Wildlife 2000—modeling habitat relationships of terrestrial vertebrates     

Gregor T. Auble 《Estuaries and Coasts》1988,11(3):212-213

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Über Die Verstärkten Südlichen und Südöstlichen Winde in Mitteleuropa     

Zdeněk Gregor 《Studia Geophysica et Geodaetica》1958,2(1):71-79

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Non-destructive damage evaluation of a structure from limited modal parameters     

Klaus Gregor Topole  Norris Stubbs 《地震工程与结构动力学》1995,24(11):1427-1436

A method to predict structural damage in its location and severity from modal characteristics of the damaged structure is proposed. No a priori knowledge of the modal characteristics of a corresponding baseline structure is required in the proposed formulation. Instead, information on the geometry of the structure which is reflected in its mass and stiffness distribution is needed. From matrix structural analysis, a system of equations is generated which relates the relative change of stiffness of structural members to a load vector generated from modal parameters of the damaged structure. Different solution techniques are suggested to determine the damage from the generated equations. The feasibility of the proposed formulation is demonstrated via a numerical example of a 10-storey building. Further, an error investigation on the error in the damage predictions due to uncertainties in the input data is carried out.  相似文献   

Ca-rich Ilvaite-Epidote-Hydrogarnet Endoskarns: a Record of Late-Magmatic Fluid Influx into the Persodic Ilimaussaq Complex, South Greenland     

Graser  Gesa; Markl  Gregor 《Journal of Petrology》2008,49(2):239-265

Endoskarn assemblages involving the Ca-silicates ilvaite, epidoteand Ca-rich garnet occur along fracture zones in the persodicIlímaussaq intrusion, South Greenland. The 1·16Ga intrusion solidified at a depth of about 3–4 km, belowa cover of sandstones and pillow-basalts of the Eriksfjord Formation.In contrast to typical skarn assemblages, the Ilímaussaqendoskarns contain albite as a main phase and they did not formin metacarbonate rocks, as these are completely lacking in thevicinity of Ilímaussaq. Instead, they record late- topost-magmatic interaction of possibly external Ca-rich fluidswith the alkaline to agpaitic magmatic rocks. Accordingly, endoskarntextures clearly reflect the magmatic textures of the precursorrocks. Phase relations in two endoskarn varieties with epidote+ albite + andradite-rich garnet ± ilvaite ± retrogradeprehnite suggest their formation at about 500°C at highoxygen fugacities slightly above the hematite–magnetiteoxygen buffer [FMQ (fayalite–magnetite–quartz) +5 to FMQ + 7] with later small modifications as a result offluid influx or cooling of the original fluid at about 300–350°C(formation of prehnite) and at about 200–250°C (oxygenisotopic re-equilibration of the albite). One model for theformation of the observed assemblages is the decomposition ofCa-bearing minerals, such as primary eudialyte, clinopyroxeneor ternary feldspar, and redistribution of the Ca by a metasomatizinglate-magmatic fluid. Stable isotope (O, H) investigations, however,favour a model in which seawater was the metasomatizing fluid,which entered the Eriksfjord basalts above the intrusion, reactedwith them (spilitization) and brought about 10^–3 mol/lCa along fractures into the metasomatized rocks. Fluid–rockinteraction in the Eriksfjord basalts is documented by abundantchlorite–epidote–quartz assemblages; high fluid/rockratios allowed the fluid to retain its seawater oxygen isotopecomposition. KEY WORDS: agpaite; endoskarn; Ilímaussaq; ilvaite; metasomatism; seawater  相似文献   

REE systematics of fluorides,calcite and siderite in peralkaline plutonic rocks from the Gardar Province,South Greenland     

Johannes Schönenberger  Jasmin Köhler  Gregor Markl 《Chemical Geology》2008,247(1-2):16-35

The Gardar failed-rift Province is world-famous for its (per-)alkaline plutonic rocks. Elevated contents of F in the mantle source and F-enrichment in the parental melts have been suggested to account for the peculiarities of the Gardar rocks (e.g. their rare mineralogy, extreme enrichment of HFSE elements, Be or REE in the Ilímaussaq agpaites, and the formation of the unique Ivigtut cryolite deposit). To constrain the formation and chemical evolution of F-bearing melts and fluids, fluorides (fluorite, cryolite, villiaumite, cryolithionite), calcite and siderite from the Ilímaussaq, Motzfeldt and Ivigtut complexes were analysed for their trace element content focusing on the rare earth elements and yttrium (REE).The various generations of fluorite occurring in the granitic Ivigtut, agpaitic Ilímaussaq and miaskitic to agpaitic Motzfeldt intrusions all share a negative Eu anomaly which is attributed to (earlier) feldspar fractionation in the parental alkali basaltic melts. This interpretation is supported by the abundance of anorthositic xenoliths in many Gardar plutonic rocks.The primary magmatic fluorites from Ilímaussaq and Motzfeldt display very similar REE patterns suggesting a formation from closely related parental melts under similar conditions. Hydrothermal fluorites from these intrusions were used to constrain the multiple effects responsible for the incorporation of trace elements into fluorides: temperature dependence, fluid migration/interaction and complexation resulting in REE fractionation. Generally, the REE patterns of Gardar fluorides reflect the evolution and migration of a F/CO₂-rich fluid leading to the formation of fluorite and fluorite/calcite veins. In certain units, this fluid inherited the REE patterns of altered host rocks. In addition, there is evidence of an even younger fluid of high REE abundance which resulted in highly variable REE concentrations (up to three orders of magnitude) within one sample of hydrothermal fluorite.The REE patterns of the granitic Ivigtut intrusion show flat to slightly heavy-REE-enriched patterns characterised by a strong tetrad effect. This effect is interpreted to record extensive fluid–rock interaction in highly fractionated, Si-rich systems.Interestingly, the fluorides appear to record different source REE patterns, as the spatially close Motzfeldt and Ilímaussaq intrusions show strong similarities and contrast with the Ivigtut intrusion located 100 km NE. These variations may be attributed to differences in the tectonic position of the intrusions or mantle heterogeneities.  相似文献